Effect of lanthanum doping on water content and diffusion properties of corundum for producing transparent ceramics

The effect of doping corundum with lanthanum on the content of water and other gas impurities, on the diffusion characteristics, on the unit cell size and static strength of fine-crystalline corundum synthesized under thermovapours conditions in a supercritical water fluid was studied.Content, release and diffusion coefficients of water and other volatile impurities in corundum were measured by kinetic thermodesorption mass spectrometry. Water is the main volatile impurity in fine-crystalline corundum. It was found that the introduction of lanthanum into the structure of corundum reduces several times the content of water and other gas-liquid impurities. An increase in the diffusion coefficient of water during the doping of corundum with lanthanum leads to an increase in the degassing rate of fine-crystalline raw materials. When doping corundum, lanthanum, being localized in structural defects, not only displaces structural hydroxyl groups with the formation of strong aluminate-like bonds, but also decreases in the unit cell and increases in the average static strength of the crystals. La-doped corundum, due to the reduced content of water and other gas impurities, is a promising raw material for the production of transparent ceramics.     

Crack initiation and propagation in braided SiC/SiC composite tubes: Effect of braiding angle

Crack initiation and propagation in three braided SiC/SiC composite tubes with different braiding angles are investigated by in situ tensile tests with synchrotron micro-computed tomography. Crack networks are precisely detected after an image subtraction procedure based on Digital Volume Correlation. FFT based simulations are performed on the full-resolution 3D images to assess elastic stress/strain fields. Quantitative measurements of the crack geometries are performed using a novel method based on grey levels. The results show that braiding angle has no obvious effect on the location of crack onsets (initiation always occurs at tow interfaces), whereas it significantly affects the paths of crack propagation. This work provides an explicit demonstration of the crack propagation scenarios with respect to the mesoscopic fibre architectures.     

The effect of baking time,fillet radius,and hardness on the lifecycles of pole fastening screws in an electric motor with hydrogen embrittlement

In order to protect bolts from corrosion, electroplating such as zinc plating is widely used. However, hydrogen can easily penetrate or diffuse into the vacancies and dislocations between the lattices of bolt steel during electroplating. As the diffused hydrogen defects inside the lattice are in gaseous form, small cracks can easily be produced due to high pressure from the hydrogen gas. In this research, in order to determine the root cause of the fracture in pole fastening screws resulting from hydrogen embrittlement in typical electric motors, additional factors that accelerate hydrogen embrittlement fracture were selectively applied, including a small fillet in the head–shank transition and excessive hardness, and parametric study was performed experimentally.     

Measurements of neutron induced nucleation

The paper describes new experimental evidence on the effects of fast neutron irradiation on the nucleation of bubbles in superheated demineralized water during sudden depressurization. The experimental range covered strating pressures of (0.33–6.0) MPa. It was shown that fast neutron irradiation causes significant increases in the bubble formation for specified conditions of pressure, temperature and rate of blowdown. A mechanistic interpretation of the measurements based on a thermodynamic model was included, and comparison was made, in terms of void fraction, with the experimental results.     

Plastic collapse of pipe bends under combined internal pressure and in-plane bending

Plastic collapse of pipe bends with attached straight pipes under combined internal pressure and in-plane closing moment is investigated by elastic–plastic finite element analysis. Three load histories are investigated, proportional loading, sequential pressure–moment loading and sequential moment–pressure loading. Three categories of ductile failure load are defined: limit load, plastic load (with associated criteria of collapse) and instability loads. The results show that theoretical limit analysis is not conservative for all the load combinations considered. The calculated plastic load is dependent on the plastic collapse criteria used. The plastic instability load gives an objective measure of failure and accounts for the effects of large deformations. The proportional and pressure–moment load cases exhibit significant geometric strengthening, whereas the moment–pressure load case exhibits significant geometric weakening.     

^60Coγ射线对刚地弓形虫缓殖子感染性的影响

应用不同剂量的~(60)Coγ射线照射含NT株弓形虫包囊的鼠脑匀浆后,以0.4％胰蛋白酶液消化,使弓形虫缓殖子从包囊中释放出来,并用生理盐水作连续10倍稀释,使成为含不同数量缓殖子的悬液,将此悬液接种小鼠,用生物检测方法确定其感染性。另设未经照射处理的缓殖子悬液感染小鼠的对照组。结果表明,γ射线0.55kGy剂量为控制鼠脑中NT株弓形虫感染性的最小有效剂量。γ射线0.1kGy剂量对弓形虫缓殖子感染性无明显影响,而0.45kGy照射后,其感染性较前者下降了10~4倍。     

A comparison of procedures for estimating the impact of nondensable gases on steam condensation taking into account the interaction of power engineering processes in the primary circuit of a nuclear power installation

We consider two procedures for evaluating the influence of nondensables on steam condensation taking into account the integral effect from interaction between the water-chemistry and thermal-hydrodynamic processes occurring in the primary coolant circuit of a nuclear power installation (NPI). Results from calculations of the passive safety system of an NPI are given.     

New high concentration–high temperature hydrogenation method for slow strain rate tensile tests

The aim of the present paper is to propose an innovative hydrogenation method based on metal hydride dissociation.By heating metal hydride, high pressure of molecular hydrogen is generated, which can be used to promote diffusion through the steel, resulting in very high atomic hydrogen concentration.This new hydrogenation method was tested on a F82H steel, a Reduced Activation Ferritic/Martensitic (RAFM) steel developed for nuclear fusion application, where high temperature Hydrogen Embrittlement (HE) is a matter of serious concern.The main goal of this study is to propose a methodology to perform tensile tests on steel at high temperature and high hydrogen contents.The technique is easy and cheap. Furthermore, by using different metal hydrides and tuning temperatures, different hydrogen concentrations can be tested.     

Vortex structure in high-T c ceramic superconductors

We consider penetration of magnetic flux in the rare earth ceramic superconductors within the framework of a generalized Ginzburg-Landau theory, based on the coexistence of antiferromagnetism and superconductivity. We study vortex structure produced for a magnetic field close to . We make a new prediction that may serve to test the theory experimentally.     

Development of materials specifications and emplacement procedures for backfilling nuclear fuel waste vaults

Atomic Energy of Canada Limited and Ontario Hydro are conducting a research program to assess the environmental impact and safety of the concept of disposal of nuclear fuel waste in an underground vault in plutonic rock of the Canadian Shield. The Vault Sealing Program, one of the components of the Nuclear Fuel Waste Management Program, is concerned with the development of materials specifications and emplacement procedures for backfilling the vault. Backfilling materials would surround the nuclear waste containers and fill all vault openings to minimize leaching and movement of radionuclides. This paper presents the procedure followed to select candidate backfill materials, the integration of mathematical modelling studies and physical testing for the definition of materials specifications, and the principal elements of the recommended handling and emplacement systems.